Evacuation of Hexavalent Chromium from an Aqueous Solution by Application of Chitosan Based Activated Carbon Prepared from Butea monosperma Bark
Asian Journal of Environment & Ecology,
Page 72-81
DOI:
10.9734/ajee/2022/v18i130306
Abstract
Industrial waste water may pollute the environment because of the presence of heavy metal ions bonded together. Heavy metal is a major source of pollution and harm to the environment across the world. Biological and environmental damage is caused by heavy metal contamination of drinking water and wastewater. Toxic, non-biodegradable, and long-lasting, they are an imperative must to remove. Environmental pollution is exacerbated by the presence of hexavalent chromium metal ion in waste water from numerous industrial facilities. Standard physical and chemical treatment procedures for removing hexavalent chromium are documented in the literature. In addition to being expensive and energy consuming, these processes appear to also result in the accumulation of hazardous byproducts. The current study used chitosan-coated Butea monosperma bark activated carbon to extract hexavalent chromium from an aqueous solution. The batch experiment was used to investigate pH effect, time of contact with adsorbent, adsorbent dose, and the starting concentration of Cr (VI) ions. The pH of the biosorbent was found to be optimum at three for Cr(VI) sorption. The elimination of Cr(VI) from the solution will be accelerated with rise of contact time. Up to 94% more Cr (VI) can be extracted for every unit increase in adsorbent dose. As the blood level of Cr (VI) increased, so did the clearance rate. In this study, researchers discovered that pre-treated biosorbent was an excellent material for eliminating of Cr(VI) ions from contaminated water.
Keywords:
- Biosorption
- Butea Monosperma Bark (BMB)
- chitosan
- hexavalent chromium
How to Cite
Hunge, S. S. (2022). Evacuation of Hexavalent Chromium from an Aqueous Solution by Application of Chitosan Based Activated Carbon Prepared from Butea monosperma Bark. Asian Journal of Environment & Ecology, 18(1), 72-81. https://doi.org/10.9734/ajee/2022/v18i130306
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Thi ND. Evaluating the Removal of Hexavalent Chromium (Cr -VI) in Wastewater by Low-Cost Adsorbent Modified from Waste Fly Ash, Chemical Engineering Transactions. 2021;89:547-552.
Wenjun jiang, Miguel Pelaez, Dionysios D Dionysiou, Mohammed H Entezari, Dimitra Tsoutsou, Kevin O Shea. Chromium (VI) removal by maghemite nanoparticles. Chemical Engg. Journal. 2013;222:527-533.
Anupam K, Dutta S, Bhattacharjee C, Datta S. Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: Optimisation through response surface methodology. Chemical Engineering Journal. 2011 Sep 1;173(1):135-43.
Polowczyk I, Urbano BF, Rivas BL, Bryjak M, Kabay N. Equilibrium and kinetic study of chromium sorption on resins with quaternary ammonium and N-methyl-D-glucamine groups. Chemical Engineering Journal. 2016 Jan 15;284:395-404.
Selvaraj K, Manonmani S, Pattabhi S. Removal of hexavalent chromium using distillery sludge. Bioresource Technology. 2003 Sep 1;89(2):207-11.
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Nigam M, Rajoriya S, Singh SR, Kumar P. Adsorption of Cr (VI) ion from tannery wastewater on tea waste: Kinetics, equilibrium and thermodynamics studies, Journal of Environmental Chemical Engineering. 2019;7:103188.
Raji C, Anirudhan TS. Batch Cr (VI) removal by polyacrylamide grafted sawdust: kinetics and thermodynamics, Water Research. 1998;32:3772–3780.
Tiravanti G, Petruzzelli D, Passino R. Pretreatment of tannery wastewaters by an ion exchange process for Cr(III) removal and recovery, Water Science Technology. 1997;36:197–206.
Shi T, Wanga Z, Liub Y, Jiaa S, Changminga D. Removal of hexavalent chromium from aqueous solutions by D301, D314 and D354 anion-exchange resins. Journal of Hazardous Material. 2009;161:900–906.,
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Kozlowski CA, Walkowiak W. Removal of chromium (VI) from aqueous solution by polymer inclusion membranes, Water Research. 2002;36:4870–4876.
Dermentzis K, Christoforidis A, Valsamidou E, Lazaridou A, Kokkinos N. Removal of hexavalent chromium from electroplating wastewater by electrocoagulation with iron electrodes, Global NEST Journal. 2011;13:412–418.
Ali I, Asim M, Khan TA. Low cost adsorbents for removal of organic pollutants from wastewater, Journal of Environmental Management. 2012;113: 70–183.
Tahir SS, Naseem R. Removal of Cr (III) from tannery wastewater by adsorption onto bentonite clay, Separation and Purification Technology. 2007;53:312– 321.
Hossain KFB, Sikder MdT, Rahman MdM, Uddin MdK, Kurasaki M. Investigation of Chromium Removal Efficacy from Tannery Effluent by Synthesized Chitosan from Crab Shell, Arabian Journal for Science and Engineering. 2017;42:1569-1577.
Mohan D, Singh KP, Singh VK. Removal of hexavalent chromium from aqueous solution using low-cost activated carbons derived from agricultural waste materials and activated carbon fabric cloth. Industrial and Engineering Chemistry Research. 2005;44:1027–1042.
Mohan D, Singh KP, Singh VK. Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth. Journal of Hazardous Materials. 2006;135(1–3):280–295.
Han X, Wong YS, Wong MH, Tam NF. Biosorption and bioreduction of Cr (VI) by a microalgal isolate, Chlorella miniata. Journal of hazardous materials. 2007 Jul 19;146(1-2):65-72.
Park D, Lim SR, Yun YS, Park JM. Reliable evidences that the removal mechanism of hexavalent chromium by natural biomaterials is adsorption-coupled reduction. Chemosphere. 2007 Dec 1;70(2):298-305.
Singh K, Giri BS, Sahi A, Geed SR, Kureel MK, Singh S, Dubey SK, Rai BN, Kumar S, Upadhyay SN, Singh RS. Biofiltration of xylene using wood charcoal as the biofilter media under transient and high loading conditions. Bioresource Technology. 2017 Oct 1;242:351-8.
Rajoriya S, Haquiqi A, Chauhan B, Tyagi G, Pundir AS, Jain AK., Influence of Adsorption Process Parameters on the Removal of Hexavalent Chromium (Cr(VI)) from Wastewater: A Review, Journal of Environmental Treatment Techniques. 2020;8 597- 603.
Khezami L, Capart R. Removal of chromium (VI) from aqueous solution by activated carbons: kinetic and equilibrium studies. Journal of hazardous materials. 2005 Aug 31;123(1-3):223-31.
Tsoutsou, Kevin O Shea., Chromium (VI) removal by magnetite nanoparticles. Chemical Engineering Journal. 2013. 222;527-533.
Innousa Zongo, Jean Pierre Leclerc, Hama Amadou Maiga, joseph Wethe, Francois Lapicque. Removal of Hexavalent chromium from industrial wastewater by electrocoagulation: A comprehensive comparison of aluminium and iron electrodes. Separation and Purification Technology. 2009;66:159-166.
Stevan Luther, Nathan Borfeld, Jisoo Kim, Parsons JG., Removal of arsenic from aqueous solution: A study of the effects of pH and interfering ions using iron oxide nanomaterials. Microchemical Journal. 2012;101:30-36.
Sonia Recillas, Ana Garcia, Edgar Gonzalez, Eudald Casals, Victor Puntes, Antoni Sanchez, Xavier Font., Use of CeO2, TiO2 and Fe3O4 nanoparticles for the removal of lead from water Toxicity of nanoparticles and derived compounds. Desalination. 2011;277:213-220.
Ibrahim MB. Thermodynamics and Adsorption Efficiencies of Maize Cob and Sawdust for the Remediation of Toxic Metals from Wastewater. Journal of Geoscience and Environment Protection. 2013;1(2):18-21.
Ibrahim MB, Jimoh WLO. Thermodynamics and Adsorption Isotherms for the Biosorption of Cr(VI), Ni(II) and Cd(II) onto Maize Cob. Chemsearch Journal. 2012;3(1):7-12.
Kobya M. Removal of Cr (VI) from aqueous solution by adsorption onto hazelnut shell activated carbon: kinetic and equilibrium studies. Bioresource Technology. 2004;91:317-321.
Owalude SO, Tella AC. Removal of Hexavalent Chromium from Aqueous Solution by Adsorption on Modified Groundnut Hull. Beni-Suef University Journal of Basic and Applied Science. 2016;5(4):377-388.
Kumari P. Application of sugarcane bagasse for the removal of Cr(VI) and Zn(II) from aqueous solution. International Research Journal of Engineering and Technology. 2017;4(2):1670-1673.
Sharma PK, Ayub S, Tripath CN. Isotherms Describing Physical Adsorption of Cr(VI) from Aqueous Solution using Various Agricultural Wastes s Adsorbents. Cogent Engineering. 2016;3:1-20.
Mekonnen E, Yitbarek M, Soreta TR. Kinetic and Thermodynamic Studies of the Adsorption of Cr(VI) onto Some Selected Local Adsorbents. South African Journal of Chemistry. 2015;68:45-52,
Malkoc E, Nuhoglu Y. Potential Tea Factory Waste for Chromium (VI) Removal from Aqueous Solution; Thermodynamic and Kinetic Studies. Separation Purification Technology. 2007;54:291-298.
Demiral H, Demiral I, Tumsek F, Karabacakoglu B. Adsorption of Chromium (VI) from Aqueous Solution by Activated Carbon Derived from Olive Bagasse and Applicability of Different Adsorption Models. Chemical Engineering Journal. 2008;144:188-196.
Govindarajan C, Ramasubramanium S Gomathi T, Narmadha Devi, Sudha PN. Sorption studies of Cr (VI) from aqueous solution using nanaochitosan –carboxymethyl cellulose blend, Arch. Appl. Sci.Res. 2011;3(4):127-138.
ISSN:0975-508.
Nomanbhay SM, Palanisamy K. Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal, Electronic Journal of Biotechnology. 200;8(1). ISSN:0717-3458.
Yu Ting Zhou, Hua Li Nie, Christopher Branford White, Zhi Yan He, Li Min Zhu. Removal of Cu2+ from aqueous solution by chitosan coated magnetic nano particles modified with Į- ketoglutaric acid. Journal of Colloid and Interface Science. 2009;330:29-37
Kannan N, Sundaram MM. Kinetics and mechanism of removal of methylene blue by adsorption on various carbons-A comparative study. Dyes Pigm. 2001;51(1):25-40.
Malise L, Rutto H, Seodigeng T, Sibali L, Ndibewu P. Adsorption of Lead Ions onto Chemical Activated Carbon Derived from Waste Tire Pyrolysis Char: Equilibrium and Kinetics Studies, Chemical Engineering Transactions. 2020;82:421-426.
Ru J, Wang X, Wang F, Cui X, Du X, Lu X, Ui .O series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: Synthesis, applications and adsorption mechanism, Ecotoxicology and Environmental Safety. 2021;208:111577.
Guo X, Liu A, Lu J, Niu X, Jiang M, Ma Y, Liu X, Li M. Adsorption Mechanism of Hexavalent Chromium on Biochar: Kinetic, Thermodynamic, and Characterization Studies, ACS Omega. 2020;5(42):27323-27331.
Abbas A, Al-Amer AM, Laoui T, Al-Marri MJ, Nasser MS, Khraisheh M, Atieh MA. Heavy metal removal from aqueous solution by advanced carbon nanotubes: critical review of adsorption applications, Separation and Purification Technology. 2016;157:141-161,
Owalude SO, Tella AC. Removal of hexavalent chromium from aqueous solutions by adsorption on modified groundnut hull, Benisuef university. Journal of Basic and Applied Sciences. 2016;5:377–388.
Thi ND. Evaluating the Removal of Hexavalent Chromium (Cr -VI) in Wastewater by Low-Cost Adsorbent Modified from Waste Fly Ash, Chemical Engineering Transactions. 2021;89:547-552.
Wenjun jiang, Miguel Pelaez, Dionysios D Dionysiou, Mohammed H Entezari, Dimitra Tsoutsou, Kevin O Shea. Chromium (VI) removal by maghemite nanoparticles. Chemical Engg. Journal. 2013;222:527-533.
Anupam K, Dutta S, Bhattacharjee C, Datta S. Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: Optimisation through response surface methodology. Chemical Engineering Journal. 2011 Sep 1;173(1):135-43.
Polowczyk I, Urbano BF, Rivas BL, Bryjak M, Kabay N. Equilibrium and kinetic study of chromium sorption on resins with quaternary ammonium and N-methyl-D-glucamine groups. Chemical Engineering Journal. 2016 Jan 15;284:395-404.
Selvaraj K, Manonmani S, Pattabhi S. Removal of hexavalent chromium using distillery sludge. Bioresource Technology. 2003 Sep 1;89(2):207-11.
Browning E. Chromium in Toxicity of Industrial Metals, Butterworths and Co., London, UK, 2nd edition; 1969.
Cieślak-Golonka M. Toxic and mutagenic effects of chromium (VI). A review. Polyhedron. 1996 Aug 5;15(21):3667-89.
WHO, 2nd ed. Guidelines for Drinking Water Quality vol. 1, World Health Organization. 1993;2016.
Nigam M, Rajoriya S, Singh SR, Kumar P. Adsorption of Cr (VI) ion from tannery wastewater on tea waste: Kinetics, equilibrium and thermodynamics studies, Journal of Environmental Chemical Engineering. 2019;7:103188.
Raji C, Anirudhan TS. Batch Cr (VI) removal by polyacrylamide grafted sawdust: kinetics and thermodynamics, Water Research. 1998;32:3772–3780.
Tiravanti G, Petruzzelli D, Passino R. Pretreatment of tannery wastewaters by an ion exchange process for Cr(III) removal and recovery, Water Science Technology. 1997;36:197–206.
Shi T, Wanga Z, Liub Y, Jiaa S, Changminga D. Removal of hexavalent chromium from aqueous solutions by D301, D314 and D354 anion-exchange resins. Journal of Hazardous Material. 2009;161:900–906.,
Mohammadi T, Moheb A, Sadrzadeh M, Razmi A. Modeling of metal ion removal from wastewater by electrodialysis, Separation and Purification Technology. 2005;41:73–82.
Song Z, Williams CJ, Edyvean RGJ. Treatment of tannery wastewater by chemical coagulation, Desalination. 2004;164:249–261.
Assadi A, Dehghani MH, Rastkari N, Nasseri S, Mahvi AH. Photocatalytic reduction of hexavalent chromium in aqueous solution with zinc oxide nanoparticles and hydrogen peroxide, Environment Protection Engineering. 2012;38:5–16.
Kozlowski CA, Walkowiak W. Removal of chromium (VI) from aqueous solution by polymer inclusion membranes, Water Research. 2002;36:4870–4876.
Dermentzis K, Christoforidis A, Valsamidou E, Lazaridou A, Kokkinos N. Removal of hexavalent chromium from electroplating wastewater by electrocoagulation with iron electrodes, Global NEST Journal. 2011;13:412–418.
Ali I, Asim M, Khan TA. Low cost adsorbents for removal of organic pollutants from wastewater, Journal of Environmental Management. 2012;113: 70–183.
Tahir SS, Naseem R. Removal of Cr (III) from tannery wastewater by adsorption onto bentonite clay, Separation and Purification Technology. 2007;53:312– 321.
Hossain KFB, Sikder MdT, Rahman MdM, Uddin MdK, Kurasaki M. Investigation of Chromium Removal Efficacy from Tannery Effluent by Synthesized Chitosan from Crab Shell, Arabian Journal for Science and Engineering. 2017;42:1569-1577.
Mohan D, Singh KP, Singh VK. Removal of hexavalent chromium from aqueous solution using low-cost activated carbons derived from agricultural waste materials and activated carbon fabric cloth. Industrial and Engineering Chemistry Research. 2005;44:1027–1042.
Mohan D, Singh KP, Singh VK. Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth. Journal of Hazardous Materials. 2006;135(1–3):280–295.
Han X, Wong YS, Wong MH, Tam NF. Biosorption and bioreduction of Cr (VI) by a microalgal isolate, Chlorella miniata. Journal of hazardous materials. 2007 Jul 19;146(1-2):65-72.
Park D, Lim SR, Yun YS, Park JM. Reliable evidences that the removal mechanism of hexavalent chromium by natural biomaterials is adsorption-coupled reduction. Chemosphere. 2007 Dec 1;70(2):298-305.
Singh K, Giri BS, Sahi A, Geed SR, Kureel MK, Singh S, Dubey SK, Rai BN, Kumar S, Upadhyay SN, Singh RS. Biofiltration of xylene using wood charcoal as the biofilter media under transient and high loading conditions. Bioresource Technology. 2017 Oct 1;242:351-8.
Rajoriya S, Haquiqi A, Chauhan B, Tyagi G, Pundir AS, Jain AK., Influence of Adsorption Process Parameters on the Removal of Hexavalent Chromium (Cr(VI)) from Wastewater: A Review, Journal of Environmental Treatment Techniques. 2020;8 597- 603.
Khezami L, Capart R. Removal of chromium (VI) from aqueous solution by activated carbons: kinetic and equilibrium studies. Journal of hazardous materials. 2005 Aug 31;123(1-3):223-31.
Tsoutsou, Kevin O Shea., Chromium (VI) removal by magnetite nanoparticles. Chemical Engineering Journal. 2013. 222;527-533.
Innousa Zongo, Jean Pierre Leclerc, Hama Amadou Maiga, joseph Wethe, Francois Lapicque. Removal of Hexavalent chromium from industrial wastewater by electrocoagulation: A comprehensive comparison of aluminium and iron electrodes. Separation and Purification Technology. 2009;66:159-166.
Stevan Luther, Nathan Borfeld, Jisoo Kim, Parsons JG., Removal of arsenic from aqueous solution: A study of the effects of pH and interfering ions using iron oxide nanomaterials. Microchemical Journal. 2012;101:30-36.
Sonia Recillas, Ana Garcia, Edgar Gonzalez, Eudald Casals, Victor Puntes, Antoni Sanchez, Xavier Font., Use of CeO2, TiO2 and Fe3O4 nanoparticles for the removal of lead from water Toxicity of nanoparticles and derived compounds. Desalination. 2011;277:213-220.
Ibrahim MB. Thermodynamics and Adsorption Efficiencies of Maize Cob and Sawdust for the Remediation of Toxic Metals from Wastewater. Journal of Geoscience and Environment Protection. 2013;1(2):18-21.
Ibrahim MB, Jimoh WLO. Thermodynamics and Adsorption Isotherms for the Biosorption of Cr(VI), Ni(II) and Cd(II) onto Maize Cob. Chemsearch Journal. 2012;3(1):7-12.
Kobya M. Removal of Cr (VI) from aqueous solution by adsorption onto hazelnut shell activated carbon: kinetic and equilibrium studies. Bioresource Technology. 2004;91:317-321.
Owalude SO, Tella AC. Removal of Hexavalent Chromium from Aqueous Solution by Adsorption on Modified Groundnut Hull. Beni-Suef University Journal of Basic and Applied Science. 2016;5(4):377-388.
Kumari P. Application of sugarcane bagasse for the removal of Cr(VI) and Zn(II) from aqueous solution. International Research Journal of Engineering and Technology. 2017;4(2):1670-1673.
Sharma PK, Ayub S, Tripath CN. Isotherms Describing Physical Adsorption of Cr(VI) from Aqueous Solution using Various Agricultural Wastes s Adsorbents. Cogent Engineering. 2016;3:1-20.
Mekonnen E, Yitbarek M, Soreta TR. Kinetic and Thermodynamic Studies of the Adsorption of Cr(VI) onto Some Selected Local Adsorbents. South African Journal of Chemistry. 2015;68:45-52,
Malkoc E, Nuhoglu Y. Potential Tea Factory Waste for Chromium (VI) Removal from Aqueous Solution; Thermodynamic and Kinetic Studies. Separation Purification Technology. 2007;54:291-298.
Demiral H, Demiral I, Tumsek F, Karabacakoglu B. Adsorption of Chromium (VI) from Aqueous Solution by Activated Carbon Derived from Olive Bagasse and Applicability of Different Adsorption Models. Chemical Engineering Journal. 2008;144:188-196.
Govindarajan C, Ramasubramanium S Gomathi T, Narmadha Devi, Sudha PN. Sorption studies of Cr (VI) from aqueous solution using nanaochitosan –carboxymethyl cellulose blend, Arch. Appl. Sci.Res. 2011;3(4):127-138.
ISSN:0975-508.
Nomanbhay SM, Palanisamy K. Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal, Electronic Journal of Biotechnology. 200;8(1). ISSN:0717-3458.
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